Watch Avatar: The Last Airbender Season 3 Episode 21 "Sozin's Comet, Part 4: Avatar Aang" online here:
http://www.tvshowslist.com/avatar-the-last-airbender-season-3-episode-21-sozins-comet-part-4-avatar-aang/
During the battle, Ozai manages to slam Aang into a sharp rock, which stabs Aang’s scar.
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