Silver is found in native form very rarely as nuggets, but more usually combined with sulfur, arsenic, antimony, or chlorine and in various ores such as argentite (Ag2S), chlorargyrite ("horn silver," AgCl), and galena (a lead ore often containing significant amounts of silver). As silver is often found in conjunction with these or alloyed with other metals such as gold, it usually must be further extracted through amalgamation or electrolysis.

Silver mining has been undertaken since early times. As silver is a precious metal often used for coins, its mining has historically often been lucrative. As with other precious metals such as gold or platinum, newly discovered deposits of silver ore have sparked silver rushes of miners seeking their fortunes. In recent centuries, large deposits were discovered and mined in the Americas, influencing the growth and development of Mexico, Andean countries such as Bolivia, Chile, and Peru, as well as Canada and the United States.

Silver has been known since ancient times. Silver is mentioned in the Book of Genesis, and slag heaps found in Asia Minor and on the islands of the Aegean Sea indicate that silver was being separated from lead as early as the 4th millennium BC. The silver mines at Laurium were very rich and helped provide a currency for the economy of Ancient Athens. It involved mining the ore in underground galleries, washing the ores and smelting it to produce the metal. Elaborate washing tables still exist at the site using rain water held in cisterns and collected during the winter months.

Extraction of silver from lead ore was widespread in Roman Britain as a result of Roman mining very soon after the conquest of the first century AD.

From the mid-15th century silver began to be extracted from copper ores in massive quantities using the liquation process creating a boost to the mining and metallurgy industries of Central Europe.
Silver is commonly extracted from ore by smelting or chemical leaching. Ore treatment by mercury amalgamation, such as in the patio process or pan amalgamation was widely used through the 1800s, but is seldom used today.

Silver is also produced during the electrolytic refining of copper and by application of the Parkes process on lead metal obtained from lead ores that contain small amounts of silver. Commercial grade fine silver is at least 99.9 percent pure silver and purities greater than 99.999 percent are available.

The 10 biggest silver mines in the world
Penasquito, Mexico
Polkowice-Sieroszowice, Poland
San Cristobal, Bolivia
Pitarrilla, Mexico
Lubin, Poland
Rudna, Poland
Gumuskoy, Turkey
Fresnillo, Mexico
Antamina, Peru
Cannington, Australia